Due to the dissolution of the base metals into the solder, solder should never be reused; once the solder's capacity to dissolve base metal has been achieved, the solder will not properly bond with the base metal and a cold solder joint with a hard and brittle crystalline appearance will usually be the result. It is good practice to remove solder from a joint prior to resoldering - desoldering wicks or vacuum desoldering equipment can be used. Desoldering wicks contain plenty of flux that will lift the contamination from the copper trace and any device leads that are present. This will leave a bright, shiny, clean junction to be resoldered.
The lower melting point of solder means it can be melted away from the base metal, leaving it mostly intact though the outer layer will be "tinned" with solder. Flux will remain which can easily be removed by abrasive or chemical processes. This tinned layer will allow solder to flow into a new joint, resulting in a new joint, as well as making the new solder flow very quickly and easily.
